Angle distortion model for predicting enediyne activation towards Bergman cyclization: an alternate to the distance theory

The kinetics of Bergman cyclization (BC) of enediynes into 1,4-benzene diradicals (also known as p-benzynes) have attracted interest ever since the discovery of natural enediynes which pointed out a surprising reactivity profile difference across enediynes with varying structural architectures. From...

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Detalles Bibliográficos
Autores principales: Bhattacharya, Prabuddha, Chakraborty, Soham, Balaji, Ashwin, Basak, Amit
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9386575/
https://www.ncbi.nlm.nih.gov/pubmed/36090394
http://dx.doi.org/10.1039/d2ra03193k

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9386575/
https://www.ncbi.nlm.nih.gov/pubmed/36090394
http://dx.doi.org/10.1039/d2ra03193k

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