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Angle distortion model for predicting enediyne activation towards Bergman cyclization: an alternate to the distance theory
The kinetics of Bergman cyclization (BC) of enediynes into 1,4-benzene diradicals (also known as p-benzynes) have attracted interest ever since the discovery of natural enediynes which pointed out a surprising reactivity profile difference across enediynes with varying structural architectures. From...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2022
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9386575/ https://www.ncbi.nlm.nih.gov/pubmed/36090394 http://dx.doi.org/10.1039/d2ra03193k |