Atomically Precise Platinum Carbonyl Nanoclusters: Synthesis, Total Structure, and Electrochemical Investigation of [Pt(27)(CO)(31)](4–) Displaying a Defective Structure

[Image: see text] The molecular Pt nanocluster [Pt(27)(CO)(31)](4–) (1(4–)) was obtained by thermal decomposition of [Pt(15)(CO)(30)](2–) in tetrahydrofuran under a H(2) atmosphere. The reaction of 1(4–) with increasing amounts of HBF(4)·Et(2)O afforded the previously reported [Pt(26)(CO)(32)](2–) (...

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Detalles Bibliográficos
Autores principales: Cesari, Cristiana, Berti, Beatrice, Funaioli, Tiziana, Femoni, Cristina, Iapalucci, Maria Carmela, Pontiroli, Daniele, Magnani, Giacomo, Riccò, Mauro, Bortoluzzi, Marco, Vivaldi, Federico Maria, Zacchini, Stefano
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9387524/
https://www.ncbi.nlm.nih.gov/pubmed/35920640
http://dx.doi.org/10.1021/acs.inorgchem.2c00965

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9387524/
https://www.ncbi.nlm.nih.gov/pubmed/35920640
http://dx.doi.org/10.1021/acs.inorgchem.2c00965

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