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Atomically Precise Platinum Carbonyl Nanoclusters: Synthesis, Total Structure, and Electrochemical Investigation of [Pt(27)(CO)(31)](4–) Displaying a Defective Structure
[Image: see text] The molecular Pt nanocluster [Pt(27)(CO)(31)](4–) (1(4–)) was obtained by thermal decomposition of [Pt(15)(CO)(30)](2–) in tetrahydrofuran under a H(2) atmosphere. The reaction of 1(4–) with increasing amounts of HBF(4)·Et(2)O afforded the previously reported [Pt(26)(CO)(32)](2–) (...
| Autores principales: | , , , , , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical Society
2022
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9387524/ https://www.ncbi.nlm.nih.gov/pubmed/35920640 http://dx.doi.org/10.1021/acs.inorgchem.2c00965 |