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Transient absorption spectroscopy of the electron transfer step in the photochemically activated polymerizations of N-ethylcarbazole and 9-phenylcarbazole

The polymerization of photoexcited N-ethylcarbazole (N-EC) in the presence of an electron acceptor begins with an electron transfer (ET) step to generate a radical cation of N-EC (N-EC˙(+)). Here, the production of N-EC˙(+) is studied on picosecond to nanosecond timescales after N-EC photoexcitation...

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Detalles Bibliográficos
Autores principales: Thornton, Georgia L., Phelps, Ryan, Orr-Ewing, Andrew J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9391922/
https://www.ncbi.nlm.nih.gov/pubmed/34612379
http://dx.doi.org/10.1039/d1cp03137f