Interference between Franck–Condon and Herzberg–Teller Terms in the Condensed-Phase Molecular Spectra of Metal-Based Tetrapyrrole Derivatives

[Image: see text] The commonly used Franck–Condon (FC) approximation is inadequate for explaining the electronic spectra of compounds that possess vibrations with substantial Herzberg–Teller (HT) couplings. Metal-based tetrapyrrole derivatives, which are ubiquitous natural pigments, often exhibit pr...

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Detalles Bibliográficos
Autores principales: Roy, Partha Pratim, Kundu, Sohang, Makri, Nancy, Fleming, Graham R.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9393888/
https://www.ncbi.nlm.nih.gov/pubmed/35929598
http://dx.doi.org/10.1021/acs.jpclett.2c01963

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9393888/
https://www.ncbi.nlm.nih.gov/pubmed/35929598
http://dx.doi.org/10.1021/acs.jpclett.2c01963

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