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Counterion-Mediated Enantioconvergent Synthesis of Axially Chiral Medium Rings

[Image: see text] There are few enantioconvergent reactions in which racemic substrates bearing multiple stereochemical features are converted into products with high levels of diastereo- and enantiocontrol. Here, we disclose a process for the highly enantio- and diastereoselective syntheses of medi...

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Detalles Bibliográficos
Autores principales: Du, Ji-Yuan, Balan, Tudor, Claridge, Tim D. W., Smith, Martin D.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9394463/
https://www.ncbi.nlm.nih.gov/pubmed/35921549
http://dx.doi.org/10.1021/jacs.2c05485