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Hydrolysis of Acetamide on Low-Index CeO(2) Surfaces: Ceria as a Deamidation and General De-esterification Catalyst
[Image: see text] Using DFT calculations and acetamide as the main example, we show that ceria is a potential catalyst for the hydrolysis of amide and similar bonds. The overall reaction is endergonic in the gas phase, yielding acetic acid and ammonia, but is slightly exergonic in the aqueous phase,...
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical Society
2022
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9397537/ https://www.ncbi.nlm.nih.gov/pubmed/36033367 http://dx.doi.org/10.1021/acscatal.2c02514 |