Dynamic Au–C σ-Bonds Leading to an Efficient Synthesis of [n]Cycloparaphenylenes (n = 9–15) by Self-Assembly

[Image: see text] The transmetalation of the digold(I) complex [Au(2)Cl(2)(dcpm)] (1) (dcpm = bis(dicyclohexylphosphino)methane) with oligophenylene diboronic acids gave the triangular macrocyclic complexes [Au(2)(C(6)H(4))(x)(dcpm)](3) (x = 3, 4, 5) with yields of over 70%. On the other hand, when...

Descripción completa

Detalles Bibliográficos
Autores principales: Yoshigoe, Yusuke, Tanji, Yohei, Hata, Yusei, Osakada, Kohtaro, Saito, Shinichi, Kayahara, Eiichi, Yamago, Shigeru, Tsuchido, Yoshitaka, Kawai, Hidetoshi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9400051/
https://www.ncbi.nlm.nih.gov/pubmed/36032535
http://dx.doi.org/10.1021/jacsau.2c00194

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9400051/
https://www.ncbi.nlm.nih.gov/pubmed/36032535
http://dx.doi.org/10.1021/jacsau.2c00194

Ejemplares similares