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Dynamic Au–C σ-Bonds Leading to an Efficient Synthesis of [n]Cycloparaphenylenes (n = 9–15) by Self-Assembly
[Image: see text] The transmetalation of the digold(I) complex [Au(2)Cl(2)(dcpm)] (1) (dcpm = bis(dicyclohexylphosphino)methane) with oligophenylene diboronic acids gave the triangular macrocyclic complexes [Au(2)(C(6)H(4))(x)(dcpm)](3) (x = 3, 4, 5) with yields of over 70%. On the other hand, when...
| Autores principales: | , , , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical Society
2022
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9400051/ https://www.ncbi.nlm.nih.gov/pubmed/36032535 http://dx.doi.org/10.1021/jacsau.2c00194 |