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Hydrogen Atom Transfer Thermodynamics of Homologous Co(III)- and Mn(III)-Superoxo Complexes: The Effect of the Metal Spin State
[Image: see text] Systematic investigations on H atom transfer (HAT) thermodynamics of metal O(2) adducts is of fundamental importance for the design of transition metal catalysts for substrate oxidation and/or oxygenation directly using O(2). Such work should help elucidate underlying electronic-st...
Autores principales: | , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Chemical Society
2022
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9400055/ https://www.ncbi.nlm.nih.gov/pubmed/36032524 http://dx.doi.org/10.1021/jacsau.2c00268 |