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Electron Shuttle in N-Heteroaromatic Ni Catalysts for Alkene Isomerization

[Image: see text] Simple N-heteroaromatic Ni(II) precatalysts, (L)NiMe(2) (L = bipy, bipym), were used for alkene isomerization. With an original reduction method using a simple borane (HB(Cat)), a low-valent Ni center was formed readily and showed good conversion when a reducing divalent lanthanide...

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Detalles Bibliográficos
Autores principales: Tricoire, Maxime, Wang, Ding, Rajeshkumar, Thayalan, Maron, Laurent, Danoun, Grégory, Nocton, Grégory
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9400170/
https://www.ncbi.nlm.nih.gov/pubmed/36032537
http://dx.doi.org/10.1021/jacsau.2c00251