Stepwise reduction of a base-stabilised ferrocenyl aluminium(iii) dihalide for the synthesis of structurally-diverse dialane species

We report the reduction of bulky ferrocenyl-based NHC-stabilised aluminium(iii) diiodide [Fc*(NHC)AlI(2)] (Fc* = 2,5-bis(3,5-di-tert-butylphenyl)-1-ferrocenyl) in different hydrocarbon solvents (hexane, benzene, toluene, and p-xylene), which results in different outcomes. Reduction in hexane with an...

Descripción completa

Detalles Bibliográficos
Autores principales: Dhara, Debabrata, Fantuzzi, Felipe, Härterich, Marcel, Dewhurst, Rian D., Krummenacher, Ivo, Arrowsmith, Merle, Pranckevicius, Conor, Braunschweig, Holger
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9400590/
https://www.ncbi.nlm.nih.gov/pubmed/36091914
http://dx.doi.org/10.1039/d2sc02783f

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9400590/
https://www.ncbi.nlm.nih.gov/pubmed/36091914
http://dx.doi.org/10.1039/d2sc02783f

Ejemplares similares