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Stepwise reduction of a base-stabilised ferrocenyl aluminium(iii) dihalide for the synthesis of structurally-diverse dialane species
We report the reduction of bulky ferrocenyl-based NHC-stabilised aluminium(iii) diiodide [Fc*(NHC)AlI(2)] (Fc* = 2,5-bis(3,5-di-tert-butylphenyl)-1-ferrocenyl) in different hydrocarbon solvents (hexane, benzene, toluene, and p-xylene), which results in different outcomes. Reduction in hexane with an...
| Autores principales: | , , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2022
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9400590/ https://www.ncbi.nlm.nih.gov/pubmed/36091914 http://dx.doi.org/10.1039/d2sc02783f |