Stabilization of a high-spin three-coordinate Fe(iii) imidyl complex by radical delocalization

High-spin, late transition metal imido complexes have attracted significant interest due to their group transfer reactivity and catalytic C–H activation of organic substrates. Reaction of a new two-coordinate iron complex, Fe{N((t)Bu)Dipp}(2) (1, Dipp = 2,6-diisopropylphenyl), with mesitylazide (Mes...

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Detalles Bibliográficos
Autores principales: Yang, Po-Chun, Yu, Kuan-Po, Hsieh, Chi-Tien, Zou, Junjie, Fang, Chia-Te, Liu, Hsin-Kuan, Pao, Chih-Wen, Deng, Liang, Cheng, Mu-Jeng, Lin, Chun-Yi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9400638/
https://www.ncbi.nlm.nih.gov/pubmed/36091897
http://dx.doi.org/10.1039/d2sc02699f

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9400638/
https://www.ncbi.nlm.nih.gov/pubmed/36091897
http://dx.doi.org/10.1039/d2sc02699f

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