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Stabilization of a high-spin three-coordinate Fe(iii) imidyl complex by radical delocalization
High-spin, late transition metal imido complexes have attracted significant interest due to their group transfer reactivity and catalytic C–H activation of organic substrates. Reaction of a new two-coordinate iron complex, Fe{N((t)Bu)Dipp}(2) (1, Dipp = 2,6-diisopropylphenyl), with mesitylazide (Mes...
| Autores principales: | , , , , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2022
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9400638/ https://www.ncbi.nlm.nih.gov/pubmed/36091897 http://dx.doi.org/10.1039/d2sc02699f |