Diastereoconvergent synthesis of anti-1,2-amino alcohols with N-containing quaternary stereocenters via selenium-catalyzed intermolecular C–H amination

We report a diastereoconvergent synthesis of anti-1,2-amino alcohols bearing N-containing quaternary stereocenters using an intermolecular direct C–H amination of homoallylic alcohol derivatives catalyzed by a phosphine selenide. Destruction of the allylic stereocenter during the selenium-catalyzed...

Descripción completa

Detalles Bibliográficos
Autores principales: Zheng, Tianyi, Berman, Janna L., Michael, Forrest E.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9400650/
https://www.ncbi.nlm.nih.gov/pubmed/36091896
http://dx.doi.org/10.1039/d2sc02648a

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9400650/
https://www.ncbi.nlm.nih.gov/pubmed/36091896
http://dx.doi.org/10.1039/d2sc02648a

Ejemplares similares