Kinetic resolution of racemic tertiary allylic alcohols through S(N)2′ reaction using a chiral bisphosphoric acid/silver(i) salt co-catalyst system

A highly efficient kinetic resolution (KR) of racemic tertiary allylic alcohols was achieved through an intramolecular allylic substitution reaction using a co-catalyst system composed of chiral bisphosphoric acid and silver carbonate. This reaction afforded enantioenriched diene monoepoxides along...

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Detalles Bibliográficos
Autores principales: Kayal, Satavisha, Kikuchi, Jun, Shinagawa, Naoya, Umemiya, Shigenobu, Terada, Masahiro
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9400685/
https://www.ncbi.nlm.nih.gov/pubmed/36091917
http://dx.doi.org/10.1039/d2sc03052g

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9400685/
https://www.ncbi.nlm.nih.gov/pubmed/36091917
http://dx.doi.org/10.1039/d2sc03052g

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