Mapping Active Site Geometry to Activity in Immobilized Frustrated Lewis Pair Catalysts

The immobilization of molecular catalysts imposes spatial constraints on their active site. We reveal that in bifunctional catalysis such constraints can also be utilized as an appealing handle to boost intrinsic activity through judicious control of the active site geometry. To demonstrate this, we...

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Detalles Bibliográficos
Autores principales: Das, Shubhajit, Laplaza, Ruben, Blaskovits, J. Terence, Corminboeuf, Clémence
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9400868/
https://www.ncbi.nlm.nih.gov/pubmed/35447004
http://dx.doi.org/10.1002/anie.202202727

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9400868/
https://www.ncbi.nlm.nih.gov/pubmed/35447004
http://dx.doi.org/10.1002/anie.202202727

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