Regio‐ and Enantioselective Intermolecular Aminofluorination of Alkenes via Iodine(I)/Iodine(III) Catalysis

The regio‐ and enantio‐selective, intermolecular vicinal fluoroamination of α‐trifluoromethyl styrenes has been achieved by enantioselective I(I)/I(III) catalysis. Leveraging C (2)‐symmetric resorcinol‐based aryl iodide catalysts, it has been possible to intercept the transient iodonium intermediate...

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Detalles Bibliográficos
Autores principales: Schäfer, Michael, Stünkel, Timo, Daniliuc, Constantin G., Gilmour, Ryan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Research Articles
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9400885/
https://www.ncbi.nlm.nih.gov/pubmed/35583965
http://dx.doi.org/10.1002/anie.202205508

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9400885/
https://www.ncbi.nlm.nih.gov/pubmed/35583965
http://dx.doi.org/10.1002/anie.202205508

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