Halogenation and Nucleophilic Quenching: Two Routes to E−X Bond Formation in Cobalt Triple‐Decker Complexes (E=As, P; X=F, Cl, Br, I)

The oxidation of [(Cp’’’Co)(2)(μ,η(2) : η(2)‐E(2))(2)] (E=As (1), P (2); Cp’’’=1,2,4‐tri(tert‐butyl)cyclopentadienyl) with halogens or halogen sources (I(2), PBr(5), PCl(5)) was investigated. For the arsenic derivative, the ionic compounds [(Cp’’’Co)(2)(μ,η(4) : η(4)−As(4)X)][Y] (X=I, Y=[As(6)I(8)](...

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Detalles Bibliográficos
Autores principales: Garbagnati, Anna, Piesch, Martin, Seidl, Michael, Balázs, Gábor, Scheer, Manfred
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Research Articles
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9400891/
https://www.ncbi.nlm.nih.gov/pubmed/35575044
http://dx.doi.org/10.1002/chem.202201026

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9400891/
https://www.ncbi.nlm.nih.gov/pubmed/35575044
http://dx.doi.org/10.1002/chem.202201026

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