Realizing 1,1‐Dehydration of Secondary Alcohols to Carbenes: Pyrrolidin‐2‐ols as a Source of Cyclic (Alkyl)(Amino)Carbenes

Herein we report secondary pyrrolidin‐2‐ols as a source of cyclic (alkyl)(amino)carbenes (CAAC) for the synthesis of CAAC‐Cu(I)‐complexes and cyclic thiones when reacted with Cu(I)‐salts and elemental sulfur, respectively, under reductive elimination of water from the carbon(IV)‐center. This result...

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Detalles Bibliográficos
Autores principales: Das, Ayan, Elvers, Benedict J., Nayak, Mithilesh Kumar, Chrysochos, Nicolas, Anga, Srinivas, Kumar, Amar, Rao, D. Krishna, Narayanan, Tharangattu N., Schulzke, Carola, Yildiz, Cem B., Jana, Anukul
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Research Articles
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9400972/
https://www.ncbi.nlm.nih.gov/pubmed/35362643
http://dx.doi.org/10.1002/anie.202202637

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9400972/
https://www.ncbi.nlm.nih.gov/pubmed/35362643
http://dx.doi.org/10.1002/anie.202202637

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