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Tuning the High‐Pressure Phase Behaviour of Highly Compressible Zeolitic Imidazolate Frameworks: From Discontinuous to Continuous Pore Closure by Linker Substitution

The high‐pressure behaviour of flexible zeolitic imidazolate frameworks (ZIFs) of the ZIF‐62 family with the chemical composition M(im)(2−x )(bim)(x) is presented (M(2+)=Zn(2+), Co(2+); im(−)=imidazolate; bim(−)=benzimidazolate, 0.02≤x≤0.37). High‐pressure powder X‐ray diffraction shows that the mat...

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Detalles Bibliográficos
Autores principales: Song, Jianbo, Pallach, Roman, Frentzel‐Beyme, Louis, Kolodzeiski, Pascal, Kieslich, Gregor, Vervoorts, Pia, Hobday, Claire L., Henke, Sebastian
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9401003/
https://www.ncbi.nlm.nih.gov/pubmed/35119185
http://dx.doi.org/10.1002/anie.202117565