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Tuning the High‐Pressure Phase Behaviour of Highly Compressible Zeolitic Imidazolate Frameworks: From Discontinuous to Continuous Pore Closure by Linker Substitution
The high‐pressure behaviour of flexible zeolitic imidazolate frameworks (ZIFs) of the ZIF‐62 family with the chemical composition M(im)(2−x )(bim)(x) is presented (M(2+)=Zn(2+), Co(2+); im(−)=imidazolate; bim(−)=benzimidazolate, 0.02≤x≤0.37). High‐pressure powder X‐ray diffraction shows that the mat...
| Autores principales: | , , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2022
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9401003/ https://www.ncbi.nlm.nih.gov/pubmed/35119185 http://dx.doi.org/10.1002/anie.202117565 |