Tricyanoborane‐Functionalized Anionic N‐Heterocyclic Carbenes: Adjustment of Charge and Stereo‐Electronic Properties

The 1‐methyl‐3‐(tricyanoborane)imidazolin‐2‐ylidenate anion (2) was obtained in high yield by deprotonation of the B(CN)(3)‐methylimidazole adduct 1. Regarding charge and stereo‐electronic properties, anion 2 closes the gap between well‐known neutral NHCs and the ditopic dianionic NHC, the 1,3‐bis(t...

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Detalles Bibliográficos
Autores principales: Zapf, Ludwig, Peters, Sven, Bertermann, Rüdiger, Radius, Udo, Finze, Maik
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Research Articles
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9401011/
https://www.ncbi.nlm.nih.gov/pubmed/35535791
http://dx.doi.org/10.1002/chem.202200275

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9401011/
https://www.ncbi.nlm.nih.gov/pubmed/35535791
http://dx.doi.org/10.1002/chem.202200275

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