Direct and Asymmetric Aldol Reactions of N‐Azidoacetyl‐1,3‐thiazolidine‐2‐thione Catalyzed by Chiral Nickel(II) Complexes. A New Approach to the Synthesis of β‐Hydroxy‐α‐Amino Acids

A direct and asymmetric triisopropylsilyltrifluoromethanesulfonate (TIPSOTf) mediated aldol reaction of N‐azidoacetyl‐1,3‐thiazolidine‐2‐thione with aromatic aldehydes catalyzed by a chiral nickel(II)‐Tol‐BINAP complex has been developed (BINAP=2,2’‐bis(diphenylphosphino)‐1,1’‐binaphthyl). The catal...

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Detalles Bibliográficos
Autores principales: Teloxa, Saul F., Mellado‐Hidalgo, Miguel, Kennington, Stuart C. D., Romea, Pedro, Urpí, Fèlix, Aullón, Gabriel, Font‐Bardia, Mercè
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Research Articles
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9401014/
https://www.ncbi.nlm.nih.gov/pubmed/35504848
http://dx.doi.org/10.1002/chem.202200671

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9401014/
https://www.ncbi.nlm.nih.gov/pubmed/35504848
http://dx.doi.org/10.1002/chem.202200671

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