London Dispersion Favors Sterically Hindered Diarylthiourea Conformers in Solution

We present an experimental and computational study on the conformers of N,N′‐diphenylthiourea substituted with different dispersion energy donor (DED) groups. While the unfolded anti–anti conformer is the most relevant for thiourea catalysis, intramolecular noncovalent interactions counterintuitivel...

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Detalles Bibliográficos
Autores principales: Rummel, Lars, Domanski, Marvin H. J., Hausmann, Heike, Becker, Jonathan, Schreiner, Peter R.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Research Articles
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9401023/
https://www.ncbi.nlm.nih.gov/pubmed/35544611
http://dx.doi.org/10.1002/anie.202204393

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9401023/
https://www.ncbi.nlm.nih.gov/pubmed/35544611
http://dx.doi.org/10.1002/anie.202204393

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