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Photo‐Induced Halogen‐Atom Transfer: Generation of Halide Radicals for Selective Hydrohalogenation Reactions

The first photo‐mediated process enabling the generation of halide radicals by Halogen‐Atom Transfer (XAT) is described. Contrary to radical transformations involving XAT reactivity, which exploit stable carbon radicals, this unique approach uses 1,2‐dihaloethanes for the generation of unstable carb...

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Detalles Bibliográficos
Autores principales: Geniller, Lilian, Taillefer, Marc, Jaroschik, Florian, Prieto, Alexis
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9401045/
https://www.ncbi.nlm.nih.gov/pubmed/35612405
http://dx.doi.org/10.1002/chem.202201495