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A Pyrene‐Triazacyclononane Anchor Affords High Operational Stability for CO(2)RR by a CNT‐Supported Histidine‐Tagged CODH

An original 1‐acetato‐4‐(1‐pyrenyl)‐1,4,7‐triazacyclononane (AcPyTACN) was synthesized for the immobilization of a His‐tagged recombinant CODH from Rhodospirillum rubrum (RrCODH) on carbon‐nanotube electrodes. The strong binding of the enzyme at the Ni‐AcPyTACN complex affords a high current density...

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Detalles Bibliográficos
Autores principales: Contaldo, Umberto, Curtil, Mathieu, Pérard, Julien, Cavazza, Christine, Le Goff, Alan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9401053/
https://www.ncbi.nlm.nih.gov/pubmed/35274429
http://dx.doi.org/10.1002/anie.202117212