Experimental and Theoretical Study of Ni(II)‐ and Pd(II)‐Promoted Double Geminal C(sp(3))−H Bond Activation Providing Facile Access to NHC Pincer Complexes: Isolated Intermediates and Mechanism

We report the first examples of metal‐promoted double geminal activation of C(sp(3))−H bonds of the N−CH(2)−N moiety in an imidazole‐type heterocycle, leading to nickel and palladium N‐heterocyclic carbene complexes under mild conditions. Reaction of the new electron‐rich diphosphine 1,3‐bis((di‐ter...

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Detalles Bibliográficos
Autores principales: He, Fengkai, Gourlaouen, Christophe, Pang, Huan, Braunstein, Pierre
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Research Articles
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9401054/
https://www.ncbi.nlm.nih.gov/pubmed/35543286
http://dx.doi.org/10.1002/chem.202200507

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9401054/
https://www.ncbi.nlm.nih.gov/pubmed/35543286
http://dx.doi.org/10.1002/chem.202200507

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