From Stable PH‐Ylides to α‐Carbanionic Phosphines as Ligands for Zwitterionic Catalysts

Although ylides are commonly used reagents in organic synthesis, the parent methylphosphine MePH(2) only exists in its phosphine form in the condensed phase. Its ylide tautomer H(3)P(+)−CH(2) (−) is considerably higher in energy. Here, we report on the formation of bis(sulfonyl)methyl‐substituted ph...

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Detalles Bibliográficos
Autores principales: Zur, Jana‐Alina, Schmidt, Michelle, Feichtner, Kai‐Stephan, Duari, Prakash, Löffler, Julian, Scherpf, Thorsten, Gessner, Viktoria H.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Research Articles
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9401067/
https://www.ncbi.nlm.nih.gov/pubmed/35644923
http://dx.doi.org/10.1002/anie.202203950

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9401067/
https://www.ncbi.nlm.nih.gov/pubmed/35644923
http://dx.doi.org/10.1002/anie.202203950

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