Cargando…
From Stable PH‐Ylides to α‐Carbanionic Phosphines as Ligands for Zwitterionic Catalysts
Although ylides are commonly used reagents in organic synthesis, the parent methylphosphine MePH(2) only exists in its phosphine form in the condensed phase. Its ylide tautomer H(3)P(+)−CH(2) (−) is considerably higher in energy. Here, we report on the formation of bis(sulfonyl)methyl‐substituted ph...
| Autores principales: | , , , , , , |
|---|---|
| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2022
|
| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9401067/ https://www.ncbi.nlm.nih.gov/pubmed/35644923 http://dx.doi.org/10.1002/anie.202203950 |