Mapping Catalyst–Solvent Interplay in Competing Carboamination/Cyclopropanation Reactions

Group 9 metals, in particular Rh(III) complexes with cyclopentadienyl ligands, are competent C−H activation catalysts. Recently, a Cp*Rh(III)‐catalyzed reaction of alkenes with N‐enoxyphthalimides showed divergent outcome based on the solvent, with carboamination favored in methanol and cyclopropana...

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Detalles Bibliográficos
Autores principales: Wodrich, Matthew D., Chang, Miyeon, Gallarati, Simone, Woźniak, Łukasz, Cramer, Nicolai, Corminboeuf, Clemence
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Research Articles
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9401068/
https://www.ncbi.nlm.nih.gov/pubmed/35522013
http://dx.doi.org/10.1002/chem.202200399

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9401068/
https://www.ncbi.nlm.nih.gov/pubmed/35522013
http://dx.doi.org/10.1002/chem.202200399

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