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On‐Surface Debromination of 2,3‐Bis(dibromomethyl)‐ and 2,3‐Bis(bromomethyl)naphthalene: Dimerization or Polymerization?

We describe the on‐surface dehalogenative homocoupling of benzylic bromides, namely bis‐bromomethyl‐ and bis‐gem‐(dibromomethyl) naphthalene as a potential route to either hydrocarbon dimers or conjugated polymers on Au(111). While bis‐gem‐(dibromomethyl) naphthalene affords different dimers with na...

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Detalles Bibliográficos
Autores principales: Tang, Yanning, Ejlli, Barbara, Niu, Kaifeng, Li, Xuechao, Hao, Zhengming, Xu, Chaojie, Zhang, Haiming, Rominger, Frank, Freudenberg, Jan, Bunz, Uwe H. F., Muellen, Klaus, Chi, Lifeng
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9401070/
https://www.ncbi.nlm.nih.gov/pubmed/35474405
http://dx.doi.org/10.1002/anie.202204123