Homolytic X‐H Bond Cleavage at a Gold(III) Hydroxide: Insights into One‐Electron Events at Gold

C(sp(3))‐H and O−H bond breaking steps in the oxidation of 1,4‐cyclohexadiene and phenol by a Au(III)‐OH complex were studied computationally. The analysis reveals that for both types of bonds the initial X−H cleavage step proceeds via concerted proton coupled electron transfer (cPCET), reflecting e...

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Detalles Bibliográficos
Autores principales: Engbers, Silène, Leach, Isaac F., Havenith, Remco W. A., Klein, Johannes E. M. N.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Research Articles
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9401072/
https://www.ncbi.nlm.nih.gov/pubmed/35506505
http://dx.doi.org/10.1002/chem.202200599

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9401072/
https://www.ncbi.nlm.nih.gov/pubmed/35506505
http://dx.doi.org/10.1002/chem.202200599

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