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Homolytic X‐H Bond Cleavage at a Gold(III) Hydroxide: Insights into One‐Electron Events at Gold
C(sp(3))‐H and O−H bond breaking steps in the oxidation of 1,4‐cyclohexadiene and phenol by a Au(III)‐OH complex were studied computationally. The analysis reveals that for both types of bonds the initial X−H cleavage step proceeds via concerted proton coupled electron transfer (cPCET), reflecting e...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2022
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9401072/ https://www.ncbi.nlm.nih.gov/pubmed/35506505 http://dx.doi.org/10.1002/chem.202200599 |