Mechanistic Investigations on Hydrogenation, Isomerization and Hydrosilylation Reactions Mediated by a Germyl‐Rhodium System

We recently disclosed a dehydrogenative double C−H bond activation reaction in the unusual pincer‐type rhodium‐germyl complex [(Ar(Mes))(2)ClGeRh] (Ar(Mes)=C(6)H(3)‐2,6‐(C(6)H(2)‐2,4,6‐Me(3))(2)). Herein we investigate the catalytic applications of this Rh/Ge system in several transformations, namel...

Descripción completa

Detalles Bibliográficos
Autores principales: Bajo, Sonia, Theulier, Cyril A., Campos, Jesús
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Research Articles
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9401076/
https://www.ncbi.nlm.nih.gov/pubmed/36032040
http://dx.doi.org/10.1002/cctc.202200157

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9401076/
https://www.ncbi.nlm.nih.gov/pubmed/36032040
http://dx.doi.org/10.1002/cctc.202200157

Ejemplares similares