Regioselective Magnesiations of Fluorinated Arenes and Heteroarenes Using Magnesium‐bis‐Diisopropylamide (MBDA) in Hydrocarbons

We report a convenient preparation of a new and storable magnesium amide (iPr(2)N)(2)Mg (magnesium‐bis‐diisopropylamide; MBDA) which proved to be especially suitable for the non‐cryogenic magnesiation of fluoro‐substituted arenes and heteroarenes providing arylmagnesium amides (ArMgDA) or bis‐hetero...

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Detalles Bibliográficos
Autores principales: Hess, Andreas, Alandini, Nurtalya, Guersoy, Yusuf C., Knochel, Paul
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9401567/
https://www.ncbi.nlm.nih.gov/pubmed/35575962
http://dx.doi.org/10.1002/anie.202206176

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9401567/
https://www.ncbi.nlm.nih.gov/pubmed/35575962
http://dx.doi.org/10.1002/anie.202206176

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