Platinum‐Catalyzed Hydrofluorination of Alkynes: Hydrogen Bonding to Indolylphosphine Ligands to Provide Fluoride Reactivity

The reaction of the Pt complexes cis‐[Pt(CH(3))(2){R(2)P(Ind)}(2)] (Ind=2‐(3‐methyl)indolyl, R=Ph (1 a), 4‐FC(6)H(4) (1 b), 4‐CF(3)C(6)H(4) (1 c)) with HF afforded the fluorido complexes trans‐[Pt(F(HF)(2))(CH(3)){R(2)P(Ind)}(2)] 2 a–c, which can be converted into trans‐[Pt(F)(CH(3)){R(2)P(Ind)}(2)]...

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Detalles Bibliográficos
Autores principales: Sander, Stefan, Braun, Thomas
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Research Articles
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9401575/
https://www.ncbi.nlm.nih.gov/pubmed/35420731
http://dx.doi.org/10.1002/anie.202204678

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9401575/
https://www.ncbi.nlm.nih.gov/pubmed/35420731
http://dx.doi.org/10.1002/anie.202204678

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