Spectroscopic Fingerprints of Cavity Formation and Solute Insertion as a Measure of Hydration Entropic Loss and Enthalpic Gain

Hydration free energies are dictated by a subtle balance of hydrophobic and hydrophilic interactions. We present here a spectroscopic approach, which gives direct access to the two main contributions: Using THz‐spectroscopy to probe the frequency range of the intermolecular stretch (150–200 cm(−1))...

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Detalles Bibliográficos
Autores principales: Pezzotti, Simone, Sebastiani, Federico, van Dam, Eliane P., Ramos, Sashary, Conti Nibali, Valeria, Schwaab, Gerhard, Havenith, Martina
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9401576/
https://www.ncbi.nlm.nih.gov/pubmed/35500074
http://dx.doi.org/10.1002/anie.202203893

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9401576/
https://www.ncbi.nlm.nih.gov/pubmed/35500074
http://dx.doi.org/10.1002/anie.202203893

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