Reductive Elimination at Pb(II) Center of an (Amino)plumbylene‐Substituted Phosphaketene: New Pathway for Phosphinidene Synthesis

A stable (amino)plumbylene‐substituted phosphaketene 3 was synthesized by the successive reactions of PbCl(2) with two anionic reagents (lithium amidophosphine and NaPCO). Of particular interest, the thermal evolution of 3, at 80 °C, leads to the transient formation of corresponding amino‐ and phosp...

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Detalles Bibliográficos
Autores principales: Timofeeva, Vladislava, Baeza, José Miguel Léon, Nougué, Raphael, Syroeshkin, Mikhail, Segundo Rojas Guerrero, Rene, Saffon‐Merceron, Nathalie, Altınbaş Özpınar, Gül, Rathjen, Saskia, Müller, Thomas, Baceiredo, Antoine, Kato, Tsuyoshi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Research Articles
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9401577/
https://www.ncbi.nlm.nih.gov/pubmed/35638144
http://dx.doi.org/10.1002/chem.202201615

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9401577/
https://www.ncbi.nlm.nih.gov/pubmed/35638144
http://dx.doi.org/10.1002/chem.202201615

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