Nickel and Copper Catalyzed ipso‐Phosphonodifluoromethylation of Arylboronic Acids with BrCF(2)P(O)(OEt)(2) for the Synthesis of Phosphonodifluoromethylarenes

A convenient method for the direct ipso‐phosphonodifluoromethylation of arylboronic acids via nickel‐copper co‐catalysis is disclosed. This work, which utilizes inexpensive first row transition metals, represents a facile alternative to the traditional palladium catalyzed approach. The method utiliz...

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Detalles Bibliográficos
Autores principales: Knieb, Alexander, Krishnamurti, Vinayak, Ispizua‐Rodriguez, Xanath, Surya Prakash, G. K.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Research Articles
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9401585/
https://www.ncbi.nlm.nih.gov/pubmed/35605186
http://dx.doi.org/10.1002/chem.202200457

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9401585/
https://www.ncbi.nlm.nih.gov/pubmed/35605186
http://dx.doi.org/10.1002/chem.202200457

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