Unexpected White Phosphorus (P(4)) Activation Modes with Silylene‐Substituted o‐Carboranes and Access to an Isolable 1,3‐Diphospha‐2,4‐disilabutadiene

New types of metal‐free white phosphorus (P(4)) activation are reported. While the phosphine‐silylene‐substituted dicarborane 1, CB‐SiP (CB=ortho‐C,C′‐C(2)B(10)H(10), Si=PhC(tBuN)(2)Si, P=P[N(tBu)CH(2)](2)), activates white phosphorus in a 2 : 1 molar ratio to yield the P(5)‐chain containing species...

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Detalles Bibliográficos
Autores principales: Xiong, Yun, Dong, Shicheng, Yao, Shenglai, Zhu, Jun, Driess, Matthias
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9401593/
https://www.ncbi.nlm.nih.gov/pubmed/35502702
http://dx.doi.org/10.1002/anie.202205358

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9401593/
https://www.ncbi.nlm.nih.gov/pubmed/35502702
http://dx.doi.org/10.1002/anie.202205358

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