Measurements and Utilization of Consistent Gibbs Energies of Transfer of Single Ions: Towards a Unified Redox Potential Scale for All Solvents

Utilizing the “ideal” ionic liquid salt bridge to measure Gibbs energies of transfer of silver ions between the solvents water, acetonitrile, propylene carbonate and dimethylformamide results in a consistent data set with a precision of 0.6 kJ mol(−1) over 87 measurements in 10 half‐cells. This form...

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Detalles Bibliográficos
Autores principales: Radtke, Valentin, Gebel, Niklas, Priester, Denis, Ermantraut, Andreas, Bäuerle, Monika, Himmel, Daniel, Stroh, Regina, Koslowski, Thorsten, Leito, Ivo, Krossing, Ingo
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Research Articles
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9401597/
https://www.ncbi.nlm.nih.gov/pubmed/35446995
http://dx.doi.org/10.1002/chem.202200509

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9401597/
https://www.ncbi.nlm.nih.gov/pubmed/35446995
http://dx.doi.org/10.1002/chem.202200509

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