Preparation of Functionalized Amides Using Dicarbamoylzincs

We report a new convenient preparation of dicarbamoylzincs of type (R(1)R(2)NCO)(2)Zn by the treatment of ZnCl(2) and formamides R(1)R(2)NCHO with LiTMP in THF (15 °C, 15 min) or by the reaction of formamides R(1)R(2)NCHO with TMP(2)Zn (25 °C, 16 h). This second method tolerates sensitive groups suc...

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Detalles Bibliográficos
Autores principales: Djukanovic, Dimitrije, Ganiek, Maximilian A., Nishi, Kohei, Karaghiosoff, Konstantin, Mashima, Kazushi, Knochel, Paul
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9401601/
https://www.ncbi.nlm.nih.gov/pubmed/35561099
http://dx.doi.org/10.1002/anie.202205440

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9401601/
https://www.ncbi.nlm.nih.gov/pubmed/35561099
http://dx.doi.org/10.1002/anie.202205440

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