2‐Aminoalkylgold Complexes: The Putative Intermediate in Au‐Catalyzed Hydroamination of Alkenes Does Not Protodemetalate

Au‐catalyzed hydroamination proceeds well for alkynes but not alkenes. We report gas‐phase binding energies of alkenes and alkynes to a cationic Au center, which indicate that differences in binding are not the origin of the disparate chemical behavior. We further report the synthesis and characteri...

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Detalles Bibliográficos
Autores principales: Gubler, Joël, Radić, Mitar, Stöferle, Yannick, Chen, Peter
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Research Articles
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9401602/
https://www.ncbi.nlm.nih.gov/pubmed/35319803
http://dx.doi.org/10.1002/chem.202200332

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9401602/
https://www.ncbi.nlm.nih.gov/pubmed/35319803
http://dx.doi.org/10.1002/chem.202200332

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