C−X Bond Activation by Palladium: Steric Shielding versus Steric Attraction

The C−X bond activation (X = H, C) of a series of substituted C(n°)−H and C(n°)−C(m°) bonds with C(n°) and C(m°) = H(3)C− (methyl, 0°), CH(3)H(2)C− (primary, 1°), (CH(3))(2)HC− (secondary, 2°), (CH(3))(3)C− (tertiary, 3°) by palladium were investigated using relativistic dispersion‐corrected density...

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Detalles Bibliográficos
Autores principales: Hansen, Thomas, Sun, Xiaobo, Dalla Tiezza, Marco, van Zeist, Willem‐Jan, van Stralen, Joost N. P., Geerke, Daan P., Wolters, Lando P., Poater, Jordi, Hamlin, Trevor A., Bickelhaupt, F. Matthias
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Research Articles
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9401605/
https://www.ncbi.nlm.nih.gov/pubmed/35420229
http://dx.doi.org/10.1002/chem.202201093

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9401605/
https://www.ncbi.nlm.nih.gov/pubmed/35420229
http://dx.doi.org/10.1002/chem.202201093

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