Cu(II) carboxylate arene C─H functionalization: Tuning for nonradical pathways

We report carbon-hydrogen acetoxylation of nondirected arenes benzene and toluene, as well as related functionalization with pivalate and 2-ethylhexanoate ester groups, using simple copper(II) [Cu(II)] salts with over 80% yield. By changing the ratio of benzene and Cu(II) salts, 2.4% conversion of b...

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Detalles Bibliográficos
Autores principales: Kong, Fanji, Chen, Shusen, Chen, Junqi, Liu, Chang, Zhu, Weihao, Dickie, Diane A., Schinski, William L., Zhang, Sen, Ess, Daniel H., Gunnoe, T. Brent
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Association for the Advancement of Science 2022
Materias:
Physical and Materials Sciences
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9401614/
https://www.ncbi.nlm.nih.gov/pubmed/36001664
http://dx.doi.org/10.1126/sciadv.add1594

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9401614/
https://www.ncbi.nlm.nih.gov/pubmed/36001664
http://dx.doi.org/10.1126/sciadv.add1594

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