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Cu(II) carboxylate arene C─H functionalization: Tuning for nonradical pathways

We report carbon-hydrogen acetoxylation of nondirected arenes benzene and toluene, as well as related functionalization with pivalate and 2-ethylhexanoate ester groups, using simple copper(II) [Cu(II)] salts with over 80% yield. By changing the ratio of benzene and Cu(II) salts, 2.4% conversion of b...

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Detalles Bibliográficos
Autores principales:	Kong, Fanji, Chen, Shusen, Chen, Junqi, Liu, Chang, Zhu, Weihao, Dickie, Diane A., Schinski, William L., Zhang, Sen, Ess, Daniel H., Gunnoe, T. Brent
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	American Association for the Advancement of Science 2022
Materias:	Physical and Materials Sciences
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9401614/ https://www.ncbi.nlm.nih.gov/pubmed/36001664 http://dx.doi.org/10.1126/sciadv.add1594

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