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Engineering Highly Reduced Molybdenum Polyoxometalates via the Incorporation of d and f Block Metal Ions

The assembly of nanoscale polyoxometalate (POM) clusters has been dominated by the highly reduced icosahedral {Mo(132)} “browns” and the toroidal {Mo(154)} “blues” which are 45 % and 18 % reduced, respectively. We hypothesised that there is space for a greater diversity of structures in this immedia...

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Detalles Bibliográficos
Autores principales: Ribó, Eduard Garrido, Bell, Nicola L., Long, De‐Liang, Cronin, Leroy
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9401863/
https://www.ncbi.nlm.nih.gov/pubmed/35257462
http://dx.doi.org/10.1002/anie.202201672