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Engineering Highly Reduced Molybdenum Polyoxometalates via the Incorporation of d and f Block Metal Ions
The assembly of nanoscale polyoxometalate (POM) clusters has been dominated by the highly reduced icosahedral {Mo(132)} “browns” and the toroidal {Mo(154)} “blues” which are 45 % and 18 % reduced, respectively. We hypothesised that there is space for a greater diversity of structures in this immedia...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
John Wiley and Sons Inc.
2022
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9401863/ https://www.ncbi.nlm.nih.gov/pubmed/35257462 http://dx.doi.org/10.1002/anie.202201672 |